{
"METABOLOMICS WORKBENCH":{"STUDY_ID":"ST000541","ANALYSIS_ID":"AN000823","VERSION":"1","CREATED_ON":"January 26, 2017, 12:45 pm"},

"PROJECT":{"PROJECT_TITLE":"Utility of canine diabetes as a model for human type 1 diabetes","PROJECT_SUMMARY":"We are examining the etiopathogenesis of canine diabetes to determine the relevance of these animals as a naturally occurring model of human type 1 diabetes. We will undertake phenotypic, metabolic, and immunologic investigations in diabetic dogs to better characterize their diabetes and attempt to identify potential biomarkers of a pre-diabetic state.","INSTITUTE":"University of Florida","DEPARTMENT":"Diabetes Institute (Wasserfall/Atkinson)/College of Veterinary Medicine (O'Kell)","LABORATORY":"Atkinson Lab","LAST_NAME":"O'Kell","FIRST_NAME":"Allison","ADDRESS":"2015 SW 16th Ave, BLDG 75, RM 387","EMAIL":"aokell@ufl.edu","PHONE":"352-294-4471 (office); 540-808-3908 (cell)"},

"STUDY":{"STUDY_TITLE":"Canine Diabetes - Preliminary Evaluation of Testing Methods","STUDY_TYPE":"Single time point blood collection","STUDY_SUMMARY":"Blood was collected from diabetic dogs and healthy control dogs. Diabetic dogs and control dogs were breed matched where possible. Timing of blood collection after a meal was matched as best as possible. Serum was frozen at -80C.","INSTITUTE":"University of Florida","DEPARTMENT":"SECIM","LAST_NAME":"O'Kell","FIRST_NAME":"Allison","ADDRESS":"2015 SW 16th Ave, BLDG 75, RM 387","EMAIL":"aokell@ufl.edu","PHONE":"352-294-4471 (office); 540-808-3908 (cell)","NUM_GROUPS":"2","TOTAL_SUBJECTS":"24"},

"SUBJECT":{"SUBJECT_TYPE":"Animal","SUBJECT_SPECIES":"Canis lupus familiaris","TAXONOMY_ID":"9615","AGE_OR_AGE_RANGE":"1 year - 15 years","WEIGHT_OR_WEIGHT_RANGE":"5 kg - 40 kg","GENDER":"Male Neutered or Female Spayed"},
"SUBJECT_SAMPLE_FACTORS":[
{
"Subject ID":"Dixie",
"Sample ID":"269031",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fed","Breed":"Mixed","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Onyx",
"Sample ID":"279436",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fed","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Cindy",
"Sample ID":"323294",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fed","Breed":"Shih Tzu","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Chewy",
"Sample ID":"309443",
"Factors":{"Health Status":"Diabetic","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Mixed","Size (S/M/L)":"Medium"}
},
{
"Subject ID":"Roxie",
"Sample ID":"321588",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Dachshund","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Annie",
"Sample ID":"325942",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Dachshund","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Max",
"Sample ID":"313390",
"Factors":{"Health Status":"Diabetic","Gender":"Neutered male","Fasting Status":"Fasted","Breed":"Miniature schnauzer","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Rooster",
"Sample ID":"216422",
"Factors":{"Health Status":"Diabetic","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Dachshund","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Evanne",
"Sample ID":"213267",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Peter",
"Sample ID":"213269",
"Factors":{"Health Status":"Diabetic","Gender":"Neutered male","Fasting Status":"Fasted","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Blaze",
"Sample ID":"325103",
"Factors":{"Health Status":"Diabetic","Gender":"Neutered male","Fasting Status":"Fasted","Breed":"Mixed","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Savannah",
"Sample ID":"325643",
"Factors":{"Health Status":"Diabetic","Gender":"Spayed female","Fasting Status":"Fed","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Gatsby",
"Sample ID":"296735",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Mixed","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Ponch",
"Sample ID":"290195",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Boomer",
"Sample ID":"326077",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Shih Tzu","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Dexter",
"Sample ID":"325932",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Mixed","Size (S/M/L)":"Medium"}
},
{
"Subject ID":"Vienna",
"Sample ID":"325866",
"Factors":{"Health Status":"Healthy","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Dachshund","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Kahluah",
"Sample ID":"295029",
"Factors":{"Health Status":"Healthy","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Miniature schnauzer","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Ross",
"Sample ID":"223169",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fed","Breed":"Dachshund","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Peyton",
"Sample ID":"228415",
"Factors":{"Health Status":"Healthy","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Jack",
"Sample ID":"255293",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fasted","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Mojito",
"Sample ID":"288261",
"Factors":{"Health Status":"Healthy","Gender":"Spayed female","Fasting Status":"Fasted","Breed":"Dachshund","Size (S/M/L)":"Small"}
},
{
"Subject ID":"Leroy",
"Sample ID":"290374",
"Factors":{"Health Status":"Healthy","Gender":"Neutered male","Fasting Status":"Fasted","Breed":"Flat coated retriever","Size (S/M/L)":"Large"}
},
{
"Subject ID":"Misty",
"Sample ID":"287971",
"Factors":{"Health Status":"Healthy","Gender":"Spayed female","Fasting Status":"Fed","Breed":"Labrador retriever","Size (S/M/L)":"Large"}
}
],
"COLLECTION":{"COLLECTION_SUMMARY":"Blood collected by peripheral venipuncture into red top tube (containing clot activator). Blood was allowed to clot, then centrifuged at 2000 g x 7 minutes between 20-30 minutes after sample collection. Serum was frozen immediately after separation (always within 1 hour of collection) at -80 C.","SAMPLE_TYPE":"Blood (serum)","COLLECTION_METHOD":"Peripheral venipuncture","COLLECTION_LOCATION":"Jugular, saphenous, or cephalic vein","COLLECTION_FREQUENCY":"Once","STORAGE_CONDITIONS":"Room temperature until centrifugation. Then -80 C immediately after separation from red cells. Serum was thawed once on ice, 100 uL aliquots taken, and aliquots re-frozen (at -80C) until use for metabolomics.","COLLECTION_VIALS":"Red top with clot activator","STORAGE_VIALS":"Cryovials (polypropylene with silicone gasket - Fisher Brand)","COLLECTION_TUBE_TEMP":"Room temperature","BLOOD_SERUM_OR_PLASMA":"Serum"},

"TREATMENT":{"TREATMENT_SUMMARY":"None"},

"SAMPLEPREP":{"SAMPLEPREP_SUMMARY":"See protocol","SAMPLEPREP_PROTOCOL_FILENAME":"Metabolomics_LCMSProtocol_plasma.pdf"},

"CHROMATOGRAPHY":{"CHROMATOGRAPHY_SUMMARY":"see protocol","CHROMATOGRAPHY_TYPE":"Reversed phase","INSTRUMENT_NAME":"Thermo Scientific Q Exactive","COLUMN_NAME":"ACE Excel 2 C18-PFP (100 x 2.1mm, 2um)"},

"ANALYSIS":{"ANALYSIS_TYPE":"MS"},

"MS":{"MS_COMMENTS":"-","INSTRUMENT_NAME":"Thermo Q Exactive Orbitrap","INSTRUMENT_TYPE":"Orbitrap","MS_TYPE":"ESI","ION_MODE":"NEGATIVE"},

"MS_METABOLITE_DATA":{
"Units":"Peak Area",

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