{
"METABOLOMICS WORKBENCH":{"STUDY_ID":"ST001432","ANALYSIS_ID":"AN002394","VERSION":"1","CREATED_ON":"July 23, 2020, 9:43 pm"},

"PROJECT":{"PROJECT_TITLE":"A Compromised Developmental Trajectory of the Infant Gut Microbiome and Metabolome in Atopic Eczema","PROJECT_SUMMARY":"Evidence is accumulating that the establishment of the gut microbiome in early life influences the development of atopic eczema. In this longitudinal study, we used integrated multi-omics analyses to infer functional mechanisms by which the microbiome modulates atopic eczema risk.","INSTITUTE":"National University of Singapore (NUS)","LAST_NAME":"Ta","FIRST_NAME":"Le Duc Huy","ADDRESS":"MD1 - Tahir Foundation Building (MD1), Level 15, Department of Paediatrics, Allergy & Immunology Division, National University of Singapore (NUS), 12 Science Drive 2. Singapore 117549","EMAIL":"huy.taleduc13@sps.nus.edu.sg","PHONE":"6596123681"},

"STUDY":{"STUDY_TITLE":"A Compromised Developmental Trajectory of the Infant Gut Microbiome and Metabolome in Atopic Eczema - (untargeted global metabolomics profiling) )","STUDY_SUMMARY":"Evidence is accumulating that the establishment of the gut microbiome in early life influences the development of atopic eczema. In this longitudinal study, we used integrated multi-omics analyses to infer functional mechanisms by which the microbiome modulates atopic eczema risk.","INSTITUTE":"National University of Singapore (NUS)","LAST_NAME":"Ta","FIRST_NAME":"Le Duc Huy","ADDRESS":"MD1 - Tahir Foundation Building (MD1), Level 15, Department of Paediatrics, Allergy & Immunology Division, National University of Singapore (NUS), 12 Science Drive 2. Singapore 117549","EMAIL":"huy.taleduc13@sps.nus.edu.sg","PHONE":"6596123681","NUM_GROUPS":"3","TOTAL_SUBJECTS":"63"},

"SUBJECT":{"SUBJECT_TYPE":"Human","SUBJECT_SPECIES":"Homo sapiens","TAXONOMY_ID":"9606"},
"SUBJECT_SAMPLE_FACTORS":[
{
"Subject ID":"-",
"Sample ID":"Global_S1",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S1.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S2",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S2.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S3",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S3.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S4",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S4.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S5",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S5.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S6",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S6.Peg"}
},
{
"Subject ID":"-",
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"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S7.Peg"}
},
{
"Subject ID":"-",
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"Additional sample data":{"RAW_FILE_NAME":"Global_S8.Peg"}
},
{
"Subject ID":"-",
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"Additional sample data":{"RAW_FILE_NAME":"Global_S9.Peg"}
},
{
"Subject ID":"-",
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"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S10.Peg"}
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Control"},
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},
{
"Subject ID":"-",
"Sample ID":"Global_S12",
"Factors":{"Treatment":"Eczema"},
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{
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{
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{
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{
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{
"Subject ID":"-",
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{
"Subject ID":"-",
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"Additional sample data":{"RAW_FILE_NAME":"Global_S21.Peg"}
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{
"Subject ID":"-",
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{
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Eczema"},
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{
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{
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{
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{
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{
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{
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{
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{
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{
"Subject ID":"-",
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Eczema"},
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{
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{
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{
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{
"Subject ID":"-",
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{
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"Factors":{"Treatment":"Control"},
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{
"Subject ID":"-",
"Sample ID":"Global_S40",
"Factors":{"Treatment":"Control"},
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{
"Subject ID":"-",
"Sample ID":"Global_S41",
"Factors":{"Treatment":"Control"},
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{
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{
"Subject ID":"-",
"Sample ID":"Global_S43",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S43.Peg"}
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Eczema"},
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{
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Eczema"},
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{
"Subject ID":"-",
"Sample ID":"Global_S47",
"Factors":{"Treatment":"Eczema"},
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{
"Subject ID":"-",
"Sample ID":"Global_S48",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S48.Peg"}
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{
"Subject ID":"-",
"Sample ID":"Global_S49",
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"Additional sample data":{"RAW_FILE_NAME":"Global_S49.Peg"}
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{
"Subject ID":"-",
"Sample ID":"Global_S50",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S50.Peg"}
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Control"},
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{
"Subject ID":"-",
"Sample ID":"Global_S52",
"Factors":{"Treatment":"Control"},
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{
"Subject ID":"-",
"Sample ID":"Global_S53",
"Factors":{"Treatment":"Control"},
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{
"Subject ID":"-",
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{
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"Factors":{"Treatment":"Control"},
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{
"Subject ID":"-",
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"Factors":{"Treatment":"Eczema"},
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{
"Subject ID":"-",
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{
"Subject ID":"-",
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
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{
"Subject ID":"-",
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},
{
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},
{
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},
{
"Subject ID":"-",
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},
{
"Subject ID":"-",
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},
{
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{
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{
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{
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{
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{
"Subject ID":"-",
"Sample ID":"Global_S155",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S155.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S156",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S156.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S157",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S157.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S158",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S158.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S159",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S159.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S160",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S160.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S161",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S161.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S162",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S162.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S163",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S163.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S164",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S164.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S165",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S165.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S166",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S166.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S167",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S167.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S168",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S168.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S169",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S169.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S170",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S170.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S171",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S171.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S172",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S172.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S173",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S173.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S174",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S174.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S175",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S175.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S176",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S176.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S177",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S177.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S178",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S178.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S179",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S179.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S180",
"Factors":{"Treatment":"Eczema"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S180.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S183",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S183.Peg"}
},
{
"Subject ID":"-",
"Sample ID":"Global_S184",
"Factors":{"Treatment":"Control"},
"Additional sample data":{"RAW_FILE_NAME":"Global_S184.Peg"}
}
],
"COLLECTION":{"COLLECTION_SUMMARY":"Stool samples were collected by the parents using sterile faeces containers and stored at -20oC at home. Samples were then transported to the lab in cold chain within 20 hours of sample collection for processing. After processing, sample were stored at -80oC until further analysis.","SAMPLE_TYPE":"Feces","STORAGE_CONDITIONS":"-80℃"},

"TREATMENT":{"TREATMENT_SUMMARY":"Control vs Eczema (Non-allergen sensitized atopic eczema, Allergen-sensitiized atopic eczema)"},

"SAMPLEPREP":{"SAMPLEPREP_SUMMARY":"For global profiling of stool metabolites, samples were randomized then processed according to our in-house protocol. Briefly, lyophilized stool sample (80 mg) was ultrasonicated with 1 mL of ice-cold extraction solvent (methanol:water [8:2]) containing 1 µg/mL d27-myristic acid as an internal standard at 4°C in a bath ultrasonicator (Elma Transsonic 460, Germany) for 30 min, and vortex-mixed for 2 min. The samples were then centrifuged at 18,000 g for 20 min at 4°C, and 0.5 mL of the supernatant was extracted carefully followed by drying at 50°C under a gentle stream of nitrogen gas (Turbovap LV, Caliper Life Sciences, Hopkinton, MA, USA). 100 µL of toluene (kept anhydrous with sodium sulfate) was added to the dry residue and evaporated completely again at 50°C under nitrogen gas to remove traces of water. The dried metabolic extract was then oximated with 50 µL of MOX (20 mg/mL) at 60°C for 2 h. Following centrifugation, 100 µL of MSTFA with 1% TMCS was added and the mixture was incubated at 60°C for 45 min to form trimethylsilyl (TMS) derivatives. Finally, 100 µL of the TMS derivatives was transferred into a GC vial and subjected to gas chromatography/time-of-flight mass spectrometry (GC/TOFMS) analysis. 50 µL of each stool extract prepared during extraction of lyophilized stool were also pooled to prepare quality control (QC) samples."},

"CHROMATOGRAPHY":{"CHROMATOGRAPHY_SUMMARY":"Helium was employed as the carrier gas at a constant flow rate of 1.5 mL/min and the injector split ratio was adjusted to 1:10. An injection volume of 1 µL was used. The injector, transfer line and ionsource temperatures were maintained at 220, 280 and 250°C, respectively. The oven temperature was programmed at 70°C for 0.2 min, increased at 9°C/min to 270°C where it was sustained for 5 min, and further increased at 40°C/min to 310°C where it was held for 11 min. The mass spectrometer was operated in the electron impact ionization mode at 70 eV. Data were acquired in full scan mode from m/z 40 to 600 with an acquisition rate of 20 spectra per second. To detect retention time shifts and facilitate Kovats retention index (RI) calculation, a standard alkane series mixture (C7-C30) was injected before every batch during sample analysis. This was accompanied by an injection of one pooled QC after every injection of 10 samples.","CHROMATOGRAPHY_TYPE":"GC","INSTRUMENT_NAME":"Agilent 7890A","COLUMN_NAME":"Agilent DB-1 DB-1 (30 m × 250 um i.d.)"},

"ANALYSIS":{"ANALYSIS_TYPE":"MS"},

"MS":{"INSTRUMENT_NAME":"Leco Pegasus III GC TOF","INSTRUMENT_TYPE":"GC-TOF","MS_TYPE":"EI","ION_MODE":"POSITIVE","MS_COMMENTS":"The mass spectrometer was operated in the electron impact ionization mode at 70 eV. Data were acquired in full scan mode from m/z 40 to 600 with an acquisition rate of 20 spectra per second."},

"MS_METABOLITE_DATA":{
"Units":"Ion Count Per Second",

"Data":[{"Metabolite":"(Methoxymethyl)trimethylsilane","Global_S1":"1.036419509","Global_S2":"1.475917758","Global_S3":"0.301975202","Global_S4":"3.662215063","Global_S5":"0.352914851","Global_S6":"1.407982024","Global_S7":"0.482914724","Global_S8":"0.32379956","Global_S9":"0.359097014","Global_S10":"0.691180701","Global_S11":"1.564335975","Global_S12":"0.000360838","Global_S13":"7.35959E-05","Global_S14":"2.875433229","Global_S15":"0.000157301","Global_S16":"0.421478233","Global_S17":"0.730173147","Global_S21":"0.376115198","Global_S22":"0.32835338","Global_S23":"0.055796302","Global_S24":"0.627391741","Global_S25":"0.189533237","Global_S26":"0.087840607","Global_S27":"6.45831E-05","Global_S28":"5.43191E-05","Global_S29":"0.610145072","Global_S30":"0.721067733","Global_S31":"0.107553814","Global_S32":"0.000164956","Global_S33":"0.407909376","Global_S34":"0.257020735","Global_S35":"0.251996549","Global_S36":"0.102425936","Global_S37":"2.111664104","Global_S38":"0.992468918","Global_S39":"0.412391506","Global_S40":"0.902429416","Global_S41":"0.201246416","Global_S42":"7.65467E-05","Global_S43":"1.307842704","Global_S44":"0.661510758","Global_S45":"1.96070986","Global_S46":"0.74092997","Global_S47":"0.435150245","Global_S48":"0.738869221","Global_S49":"0.799192459","Global_S50":"4.460139637","Global_S51":"2.43029415","Global_S52":"1.75846718","Global_S53":"0.485260706","Global_S56":"0.62506667","Global_S57":"0.289668495","Global_S58":"1.396561712","Global_S59":"1.36435652","Global_S60":"0.527497962","Global_S61":"4.80956E-05","Global_S65":"0.209826322","Global_S66":"1.256849741","Global_S67":"0.197265911","Global_S68":"0.224157923","Global_S69":"0.119623989","Global_S72":"2.99647158","Global_S73":"0.237853783","Global_S74":"0.182599791","Global_S75":"0.544550355","Global_S76":"0.000104696","Global_S77":"0.130298196","Global_S78":"0.202838196","Global_S79":"0.691678677","Global_S80":"0.216948314","Global_S81":"0.1547777","Global_S82":"0.605386495","Global_S85":"9.31207E-05","Global_S86":"0.380343086","Global_S87":"0.217439931","Global_S88":"0.810438952","Global_S89":"0.334692846","Global_S90":"1.410491049","Global_S91":"0.412792416","Global_S92":"4.85429E-05","Global_S93":"1.221890065","Global_S94":"0.199049819","Global_S95":"8.32658E-05","Global_S96":"2.871596872","Global_S97":"0.323636009","Global_S98":"1.486304441","Global_S99":"0.941917351","Global_S100":"0.000131","Global_S101":"1.453821601","Global_S102":"0.576972649","Global_S103":"8.05067E-05","Global_S104":"0.01994514","Global_S105":"0.15497586","Global_S106":"4.46244E-05","Global_S107":"0.253561841","Global_S108":"0.244890662","Global_S109":"0.002514623","Global_S110":"0.194825202","Global_S111":"0.505481801","Global_S112":"0.684694936","Global_S113":"2.565157755","Global_S114":"2.414244367","Global_S115":"0.376728849","Global_S116":"0.473076448","Global_S121":"0.38713803","Global_S122":"0.209980271","Global_S123":"0.472448471","Global_S124":"4.01516E-05","Global_S125":"0.817236931","Global_S126":"0.615786759","Global_S127":"0.631935229","Global_S131":"0.675999671","Global_S132":"0.482075535","Global_S134":"7.77555E-05","Global_S135":"1.026545834","Global_S136":"0.211485808","Global_S137":"0.692881989","Global_S138":"2.459752949","Global_S139":"0.065845957","Global_S140":"2.9694272","Global_S141":"0.534158364","Global_S142":"3.20838E-05","Global_S143":"0.000217081","Global_S144":"0.482733568","Global_S145":"0.228933819","Global_S146":"0.214239602","Global_S147":"1.120664223","Global_S148":"3.798429823","Global_S149":"0.000141791","Global_S150":"1.375077878","Global_S151":"0.108358505","Global_S152":"1.884259765","Global_S153":"1.591482521","Global_S154":"0.000101426","Global_S155":"0.113076321","Global_S156":"0.293053958","Global_S157":"2.319933446","Global_S158":"0.42258215","Global_S159":"0.608028161","Global_S160":"1.713861405","Global_S161":"1.286033007","Global_S162":"3.974985738","Global_S163":"7.62003E-05","Global_S164":"0.000102056","Global_S165":"0.000180093","Global_S166":"2.351791025","Global_S167":"0.000164342","Global_S168":"0.986280635","Global_S169":"0.259802724","Global_S170":"0.106759589","Global_S171":"0.905964632","Global_S172":"0.274822101","Global_S173":"2.693838784","Global_S174":"1.824506575","Global_S175":"1.367988292","Global_S176":"3.234504697","Global_S177":"6.57997E-05","Global_S178":"1.532271068","Global_S179":"6.352979803","Global_S180":"1.170153969","Global_S183":"1.000717502","Global_S184":"0.528074612"},{"Metabolite":"(R)-3-Hydroxybutyric acid, trimethylsilyl ether, trimethylsilyl 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2"},{"metabolite_name":"Lactose 2"},{"metabolite_name":"Lactose 2:3"},{"metabolite_name":"Lactose 2:4"},{"metabolite_name":"Lactose 2:5"},{"metabolite_name":"2-hydroxypyridine"},{"metabolite_name":"N-acetyl-D-mannosamine 1:2"},{"metabolite_name":"N-acetyl-D-mannosamine 1:3"},{"metabolite_name":"N-acetyl-D-mannosamine 1:4"},{"metabolite_name":"N-acetyl-D-mannosamine 2"},{"metabolite_name":"N-acetyl-D-mannosamine 2:2"},{"metabolite_name":"3-indolelactic acid 2"},{"metabolite_name":"1-Monooleoylglycerol trimethylsilyl ether"},{"metabolite_name":"1-O-hexadecylglycerol - bis-trimethylsilyl ether derivative"},{"metabolite_name":"1,3-Bis(trimethylsiloxy)benzene"},{"metabolite_name":"1,4-Butanediamine, N,N,N',N'-tetrakis(trimethylsilyl)-"},{"metabolite_name":"10,12-Tricosadiynoic acid, trimethylsilyl ester"},{"metabolite_name":"11-cis-Octadecenoic acid, trimethylsilyl ester"},{"metabolite_name":"1H-Indole-3-ethanamine, N,N,1-tris(trimethylsilyl)-"},{"metabolite_name":"1H-Indole-3-propanoic acid, 1-(trimethylsilyl)-, trimethylsilyl ester"},{"metabolite_name":"2-Butenedioic acid (E)-, bis(trimethylsilyl) ester"},{"metabolite_name":"2-Butenedioic acid (E)-, bis(trimethylsilyl) ester:2"},{"metabolite_name":"2-Butenedioic acid (E)-, bis(trimethylsilyl) ester:3"},{"metabolite_name":"2-Butenedioic acid (E)-, bis(trimethylsilyl) ester:4"},{"metabolite_name":"2-Butenoic acid, 3-methyl-2-[(trimethylsilyl)oxy]-, trimethylsilyl ester"},{"metabolite_name":"2-Deoxy-galactopyranose, tetrakis(trimethylsilyl)"},{"metabolite_name":"2-Deoxy-galactopyranose, tetrakis(trimethylsilyl):2"},{"metabolite_name":"2-Desoxy-pentos-3-ulose, bis(methoxime),O,O'-bis(trimethylsilyl)-:2"},{"metabolite_name":"2-Ethyl-3-trimethylsilyloxy(trimethylsilyl)butyrate"},{"metabolite_name":"2-Furanacetaldehyde, tetrahydro-à,3,4,5-tetrakis[(trimethylsilyl)oxy]-"},{"metabolite_name":"2-Hydroxyisocaproic acid, trimethylsilyl ether, trimethylsilyl ester"},{"metabolite_name":"2-Piperidinecarboxylic acid, trimethylsilyl ester"},{"metabolite_name":"2-Piperidinone"},{"metabolite_name":"2-Pyrrolidone-5-carboxylic acid, trimethylsilyl ester"},{"metabolite_name":"3-Phenyl-3-trimethylsilyloxypropanoic acid, trimethylsilyl ester"},{"metabolite_name":"3-Pyridinecarboxylic acid, trimethylsilyl ester"},{"metabolite_name":"3,3-Dichloropropyne"},{"metabolite_name":"3,4,5-Trihydroxypentanoic acid, tetrakis(trimethylsilyl)-"},{"metabolite_name":"3,6-Dioxa-2,7-disilaoctane, 2,2,4,7,7-pentamethyl-"},{"metabolite_name":"3,8-Dioxa-2,9-disiladecane, 2,2,9,9-tetramethyl-5,6-bis[[(trimethylsilyl)oxy]methyl]-"},{"metabolite_name":"4-Ketoglucose, bis(O-methyloxime), tetrakis(trimethylsilyl)"},{"metabolite_name":"4-N,N-Dimethylamino(trimethylsilyl)butyrate"},{"metabolite_name":"4-Trimethylsiloxy(trimethylsilyl)valerate"},{"metabolite_name":"5-Trimethylsilyloxy-n-valeric acid, trimethylsilyl ester"},{"metabolite_name":"5H-Cyclopenta[b]pyridine-3-carbonitrile, 6,7-dihydro-2-mercapto-"},{"metabolite_name":"9-Octadecenoic acid 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3-methyl-2-[(trimethylsilyl)oxy]-, trimethylsilyl ester"},{"metabolite_name":"Butanoic acid, 4-[(trimethylsilyl)oxy]-, trimethylsilyl ester"},{"metabolite_name":"Butanoic acid, 4-[bis(trimethylsilyl)amino]-, trimethylsilyl ester:2"},{"metabolite_name":"Cadaverine tri-TMS"},{"metabolite_name":"Cadaverine tri-TMS:2"},{"metabolite_name":"Cadaverine, N,N,N',N'-tetrakis(trimethylsilyl):2"},{"metabolite_name":"cis-4-Trimethylsilyloxy-cyclohexyl(trimethylsilyl)carboxylate"},{"metabolite_name":"Cyclohexanecarboxylic acid, trimethylsilyl ester"},{"metabolite_name":"d-Erythrotetrofuranose, tris-O-(trimethylsilyl)-"},{"metabolite_name":"d-Galactose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1E)-"},{"metabolite_name":"d-Galactose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1E)-:2"},{"metabolite_name":"d-Galactose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, (1Z)-"},{"metabolite_name":"d-Galactose, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, o-methyloxyme, 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}

}