{
"METABOLOMICS WORKBENCH":{"STUDY_ID":"ST001648","ANALYSIS_ID":"AN002694","VERSION":"1","CREATED_ON":"January 13, 2021, 9:54 am"},

"PROJECT":{"PROJECT_TITLE":"Comprehensive dissection of primary metabolites in response to diverse abiotic stress in barley at seedling stage","PROJECT_TYPE":"Artical","PROJECT_SUMMARY":"Plants will meet various abiotic stresses during their growth and development. One of the important strategies for plants to deal with the stress is involved in metabolic regulation, causing the dramatic changes of metabolite profiles. Metabolomic studies have been intensively conducted to reveal the responses of plants to abiotic stress, but most of them were limited to one or at most two abiotic stresses in a single experiment. In this study, we compared the metabolite profiles of barley seedlings exposed to seven abiotic stresses simultaneously, including drought, salt stress, aluminum (Al), cadmium (Cd), deficiency of nitrogen (N), phosphorus (P) and potassium (K). The results showed that metabolite profiles of barley under these stresses could be classified into three types: osmotic stresses (drought and salt); metal stresses (Al and Cd) and nutrient deficiencies (N, P and K deficiencies). Compared with the control, some metabolites (including polyamines, raffinose and piperonic acid) in plants exposed to all abiotic stresses changed significantly, while some other metabolites showed the specific change only under a certain abiotic stress, such as proline being largely increased by osmotic stress (drought and salinity), the P-containing metabolites being largely decreased under P deficiency, some amino acids (lysine, tyrosine, threonine, ornithine， glutamine and so on) showing the dramatic reduction in the plants exposed to N deficiencies, respectively. The current meta-analysis obtained a comprehensive view on the metabolic responses to various abiotic stress, and improved the understanding of the mechanisms for tolerance of barley to abiotic stress.","INSTITUTE":"Zhengjiang University","DEPARTMENT":"Crop Research Institute","LABORATORY":"Barley Research Group of Crop Institute","LAST_NAME":"Zhao","FIRST_NAME":"Huifang","ADDRESS":"West Lake District, 866 Yuhangtang Road","EMAIL":"11716028@zju.edu.cn","PHONE":"18888923662","FUNDING_SOURCE":"National Key R.D; Program of China; Natural Science Foundation of China; China Agriculture Research System","PUBLICATIONS":"PLANT PHYSIOLOGY A.D; BIOCHEMISTRY"},

"STUDY":{"STUDY_TITLE":"Comprehensive dissection of primary metabolites in response to diverse abiotic stress in barley at seedling stage","STUDY_TYPE":"Artical","STUDY_SUMMARY":"Plants will meet various abiotic stresses during their growth and development. One of the important strategies for plants to deal with the stress is involved in metabolic regulation, causing the dramatic changes of metabolite profiles. Metabolomic studies have been intensively conducted to reveal the responses of plants to abiotic stress, but most of them were limited to one or at most two abiotic stresses in a single experiment. In this study, we compared the metabolite profiles of barley seedlings exposed to seven abiotic stresses simultaneously, including drought, salt stress, aluminum (Al), cadmium (Cd), deficiency of nitrogen (N), phosphorus (P) and potassium (K). The results showed that metabolite profiles of barley under these stresses could be classified into three types: osmotic stresses (drought and salt); metal stresses (Al and Cd) and nutrient deficiencies (N, P and K deficiencies). Compared with the control, some metabolites (including polyamines, raffinose and piperonic acid) in plants exposed to all abiotic stresses changed significantly, while some other metabolites showed the specific change only under a certain abiotic stress, such as proline being largely increased by osmotic stress (drought and salinity), the P-containing metabolites being largely decreased under P deficiency, some amino acids (lysine, tyrosine, threonine, ornithine， glutamine and so on) showing the dramatic reduction in the plants exposed to N deficiencies, respectively. The current meta-analysis obtained a comprehensive view on the metabolic responses to various abiotic stress, and improved the understanding of the mechanisms for tolerance of barley to abiotic stress.","INSTITUTE":"Zhengjiang University","DEPARTMENT":"Crop Research Institute","LABORATORY":"Barley Research Group of Crop Institute","LAST_NAME":"Zhao","FIRST_NAME":"Huifang","ADDRESS":"West Lake District, 866 Yuhangtang Road","EMAIL":"11716028@zju.edu.cn","PHONE":"18888923662","NUM_GROUPS":"1","TOTAL_SUBJECTS":"1","NUM_MALES":"2","NUM_FEMALES":"1","PUBLICATIONS":"PLANT PHYSIOLOGY A.D; BIOCHEMISTRY"},

"SUBJECT":{"SUBJECT_TYPE":"Plant","SUBJECT_SPECIES":"Hordeum vulgare L."},
"SUBJECT_SAMPLE_FACTORS":[
{
"Subject ID":"-",
"Sample ID":"shoot-1",
"Factors":{"Treatment":"Shoot_Control-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 01.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-2",
"Factors":{"Treatment":"Shoot_Control-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 02.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-3",
"Factors":{"Treatment":"Shoot_Control-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 03.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-4",
"Factors":{"Treatment":"Shoot_Control-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 04.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-5",
"Factors":{"Treatment":"Shoot_Salt-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 05.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-6",
"Factors":{"Treatment":"Shoot_Salt-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 06.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-7",
"Factors":{"Treatment":"Shoot_Salt-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 07.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-8",
"Factors":{"Treatment":"Shoot_Salt-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 08.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-9",
"Factors":{"Treatment":"Shoot_Drought-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 09.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-10",
"Factors":{"Treatment":"Shoot_Drought-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 10.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-11",
"Factors":{"Treatment":"Shoot_Drought-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 11.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-12",
"Factors":{"Treatment":"Shoot_Drought-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 12.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-13",
"Factors":{"Treatment":"Shoot_Al-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 17.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-14",
"Factors":{"Treatment":"Shoot_Al-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 18.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-15",
"Factors":{"Treatment":"Shoot_Al-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 19.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-16",
"Factors":{"Treatment":"Shoot_Al-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 20.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-17",
"Factors":{"Treatment":"Shoot_Cd-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 21.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-18",
"Factors":{"Treatment":"Shoot_Cd-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 22.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-19",
"Factors":{"Treatment":"Shoot_Cd-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 23.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-20",
"Factors":{"Treatment":"Shoot_Cd-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 24.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-21",
"Factors":{"Treatment":"Shoot_N deficiency-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 25.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-22",
"Factors":{"Treatment":"Shoot_N deficiency-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 26.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-23",
"Factors":{"Treatment":"Shoot_N deficiency-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 27.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-24",
"Factors":{"Treatment":"Shoot_N deficiency-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 28.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-25",
"Factors":{"Treatment":"Shoot_P deficiency-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 29.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-26",
"Factors":{"Treatment":"Shoot_P deficiency-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 30.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-27",
"Factors":{"Treatment":"Shoot_P deficiency-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 31.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-28",
"Factors":{"Treatment":"Shoot_P deficiency-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 32.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-29",
"Factors":{"Treatment":"Shoot_K deficiency-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 33.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-30",
"Factors":{"Treatment":"Shoot_K deficiency-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 34.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-31",
"Factors":{"Treatment":"Shoot_K deficiency-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 35.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"shoot-32",
"Factors":{"Treatment":"Shoot_K deficiency-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 36.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-1",
"Factors":{"Treatment":"Root_Control-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 45.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-2",
"Factors":{"Treatment":"Root_Control-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 46.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-3",
"Factors":{"Treatment":"Root_Control-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 47.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-4",
"Factors":{"Treatment":"Root_Control-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 48.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-5",
"Factors":{"Treatment":"Root_Salt-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 49.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-6",
"Factors":{"Treatment":"Root_Salt-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 50.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-7",
"Factors":{"Treatment":"Root_Salt-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 51.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-8",
"Factors":{"Treatment":"Root_Salt-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 52.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-9",
"Factors":{"Treatment":"Root_Drought-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 53.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-10",
"Factors":{"Treatment":"Root_Drought-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 54.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-11",
"Factors":{"Treatment":"Root_Drought-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 55.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-12",
"Factors":{"Treatment":"Root_Drought-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 56.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-13",
"Factors":{"Treatment":"Root_Al-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 61.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-14",
"Factors":{"Treatment":"Root_Al-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 62.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-15",
"Factors":{"Treatment":"Root_Al-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 63.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-16",
"Factors":{"Treatment":"Root_Al-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 64.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-17",
"Factors":{"Treatment":"Root_Cd-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 65.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-18",
"Factors":{"Treatment":"Root_Cd-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 66.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-19",
"Factors":{"Treatment":"Root_Cd-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 67.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-20",
"Factors":{"Treatment":"Root_Cd-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 68.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-21",
"Factors":{"Treatment":"Root_N deficiency-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 69.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-22",
"Factors":{"Treatment":"Root_N deficiency-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 70.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-23",
"Factors":{"Treatment":"Root_N deficiency-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 71.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-24",
"Factors":{"Treatment":"Root_N deficiency-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 72.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-25",
"Factors":{"Treatment":"Root_P deficiency-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 73.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-26",
"Factors":{"Treatment":"Root_P deficiency-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 74.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-27",
"Factors":{"Treatment":"Root_P deficiency-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 75.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-28",
"Factors":{"Treatment":"Root_P deficiency-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 76.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-29",
"Factors":{"Treatment":"Root_K deficiency-1"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 77.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-30",
"Factors":{"Treatment":"Root_K deficiency-2"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 78.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-31",
"Factors":{"Treatment":"Root_K deficiency-3"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 79.D","Genotype":"Wild-type"}
},
{
"Subject ID":"-",
"Sample ID":"root-32",
"Factors":{"Treatment":"Root_K deficiency-4"},
"Additional sample data":{"RAW_FILE_NAME":"GCMS 80.D","Genotype":"Wild-type"}
}
],
"COLLECTION":{"COLLECTION_SUMMARY":"Barley seedlings were allowed to grow up to two-leaf-stage in the normal hydroponic solution, and then exposed to various treatments after removing endosperm for eliminating its nutrient supply. The treatments included 20% PEG for drought stress, 150 mM NaCl for salt stress, 50 μM Al3+ at pH 4.5 for aluminum stress (Al stress, at the same time the nutrient solution with pH 4.5 and without Al addition used as control), 5 μM CdCl2 for cadmium stress (Cd stress), 0 mM N for N deficiency (replace KNO3, Ca(NO3).4H2O and (NH4)6Mo7O24 with 1mM CaCl2, 1mM KH2PO4 and 0.07 mM H2MoO4), 0 mM P for P deficiency (replace NH4H2PO4 with 1mM NH4Cl), 0 mM K for K deficiency (replace KNO3 with 1mM NaNO3). The hydroponic solution was renewed every four days. After twenty days of the treatments, the plants were harvested, and fresh and dry weight were recorded quickly. The dry tissues were used for mineral element concentration analysis with three biological replicates for each treatment. Meanwhile, fresh tissues were frozen in liquid nitrogen and stored at -80 ℃ for metabolite analysis with four biological replicates for each stress treatment.","SAMPLE_TYPE":"Plant","STORAGE_CONDITIONS":"-80℃"},

"TREATMENT":{"TREATMENT_SUMMARY":"The treatments included 20% PEG for drought stress, 150 mM NaCl for salt stress, 50 μM Al3+ at pH 4.5 for aluminum stress (Al stress, at the same time the nutrient solution with pH 4.5 and without Al addition used as control), 5 μM CdCl2 for cadmium stress (Cd stress), 0 mM N for N deficiency (replace KNO3, Ca(NO3).4H2O and (NH4)6Mo7O24 with 1mM CaCl2, 1mM KH2PO4 and 0.07 mM H2MoO4), 0 mM P for P deficiency (replace NH4H2PO4 with 1mM NH4Cl), 0 mM K for K deficiency (replace KNO3 with 1mM NaNO3)."},

"SAMPLEPREP":{"SAMPLEPREP_SUMMARY":"The frozen tissue was homogenized in liquid nitrogen and approximately 100 mg of powder sample was added into 2 ml vertical centrifuge tube. Then 1.4 ml of 100% methanol (pre-cooled at -20 °C) was added and vortexed thoroughly. Then the tubes were shaken for 10 min at 70 °C, followed by centrifugation at 11,000 g for 10 min. The supernatant was transferred into a new 10 ml sterile centrifuge tube, and 750 μl chloroform (−20 °C) and 1.5 ml deionized water (4 °C) were added. The mixture was vortexed and centrifuged at 2200 g for 15 min. The upper methanol/water phase was collected for metabolite analysis. A total of 150 μl collected solution was dried in a vacuum freeze dryer. The dried residue was derivatized in 40 μl of 15 mg ml-1 methoxylamine hydrochloride in pyridine for 120 min at 37 °C, followed by reaction with 70 μl of N-Methyl-N-(trimethylsilyl) trifluoroacetamide (MSTFA) reagent for another 30 min at 37 °C. After the reaction, the reacted solution was transferred to glass vial insert in 2 ml glass bottle (Agilent, USA) for GC-MS determination. Meanwhile, one blank derivatization reaction (with reagent) was also prepared as a control."},

"CHROMATOGRAPHY":{"CHROMATOGRAPHY_TYPE":"GC","INSTRUMENT_NAME":"Agilent 7890A","COLUMN_NAME":"Agilent DB5-MS (30m x 0.25mm, 0.25um)"},

"ANALYSIS":{"ANALYSIS_TYPE":"MS"},

"MS":{"INSTRUMENT_NAME":"Agilent 7890A","INSTRUMENT_TYPE":"GC-TOF","MS_TYPE":"API","ION_MODE":"UNSPECIFIED","MS_COMMENTS":"The retention time (RT) and mass spectra of each compound were analyzed using AMDIS (Automated Mass Spectral Deconvolution and Identification System) software (http://chemdata.nist.gov/)."},

"MS_METABOLITE_DATA":{
"Units":"pmoles/l",

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}

}