m/z values QC01_Hilic_neg QC02_Hilic_neg QC03_Hilic_neg QC04_Hilic_neg QC05_Hilic_neg QC06_Hilic_neg QC07_Hilic_neg QC08_Hilic_neg A1_Hilic_neg A2_Hilic_neg A3_Hilic_neg A4_Hilic_neg A5_Hilic_neg B1_Hilic_neg B2_Hilic_neg B3_Hilic_neg B4_Hilic_neg B5_Hilic_neg C1_Hilic_neg C2_Hilic_neg C3_Hilic_neg C4_Hilic_neg C5_Hilic_neg BLK A_Hilic_neg BLK B_Hilic_neg BLK C_Hilic_neg 2.70_575.2543m/z 1223.932115 1169.899054 1292.998396 1123.334933 924.5064401 891.0726813 837.7884464 823.0284951 761.6603755 526.972911 596.8286133 757.0962943 142.5544794 1820.908734 1596.8483 1717.418444 0.207052088 453.2387489 1219.429571 752.6027855 510.2296837 1843.351687 1271.294578 0 0 0 2.94_420.1511m/z 1313.754447 1266.775167 1430.666908 1301.97124 1243.18103 1237.552841 1272.565428 1277.606739 1775.862373 1098.709307 1257.484332 523.2705827 1431.555677 1961.283649 1731.402227 1777.332446 3953.277302 1215.976403 1418.553878 1576.422448 2143.220657 1782.486794 1434.523878 879.0894257 507.6775864 590.9130992 1.43_317.2114m/z 123.6594148 174.1301519 162.4814235 146.7299626 356.2722333 352.2060411 304.4477993 285.405525 54.36594266 56.54909201 74.70202571 0 75.86663666 285.4621603 346.1558209 239.8020781 0 339.4524835 347.1509587 372.5136588 457.5723813 224.9581124 334.5762997 0 0 0 1.88_380.2169m/z 50.52893669 36.47526023 48.94194168 27.58720966 62.02484312 70.86029133 49.35619226 63.12795937 160.4275605 124.8508421 149.0874686 13.03884144 212.0911274 51.6991783 46.25376494 53.93944519 21.57813894 26.21529601 65.12098523 103.2771758 70.39493129 70.2103349 61.77782251 31.56739509 27.38162299 16.16253674 3.24_529.2866m/z 164.8846253 189.0502725 171.0848242 173.5137907 193.6282931 195.145696 194.2344288 211.2309654 255.0752758 147.0640561 181.5363349 525.861922 177.6566501 262.4500994 249.9464309 240.5240472 17.57332361 188.6641277 220.7674916 220.3734829 238.3561972 266.3264156 230.2072535 47.97615693 41.50615729 17.82071266 7.58_493.1605m/z 73.42117406 72.01253458 4.061189358 66.91852988 56.36498306 52.80226145 51.98836863 52.08731641 61.76336843 45.61025581 38.69007293 59.60266643 95.79577342 73.53136401 64.26672951 78.86609744 54.54094526 80.29489265 63.49108464 83.73721629 160.6000288 52.81151959 54.14802103 0 0 3.463950118 4.22_507.1703m/z 39.09598415 34.19695099 19.59624765 29.04555486 53.4274899 54.61625611 62.33701016 57.56085484 57.47849894 49.29866701 38.70403617 50.12903045 189.0404868 53.27859929 48.02428739 48.00555331 623.5560577 83.67097302 49.35544732 91.28830332 171.9309324 40.45762184 43.50524391 0 0 12.92178793 1.52_209.1180m/z 278.280389 279.7851505 333.1920951 367.2180362 511.8645875 500.9432315 502.0066417 525.839645 209.2184027 116.5173465 155.7964029 0 294.0169746 555.6627319 583.130852 513.9494042 0 607.6363622 604.335051 678.3996376 908.407966 467.8097165 524.550354 26.71885903 0 0 2.57_501.2212m/z 276.7818244 306.0359965 232.6166911 275.1448422 222.1419528 229.9740319 203.9636635 224.3286783 108.4658332 59.2634376 76.02695594 0 15.06447823 446.4838481 439.5219557 435.4721769 0.991708733 129.2351306 328.4638702 226.7993818 205.2616954 430.505279 312.6420994 24.38391472 0 0 2.22_206.0804m/z 40.51103049 46.00069111 62.6796582 47.31232283 76.74875139 96.24337483 102.4703705 84.60621408 37.35936704 39.41979925 32.08734274 18.16021326 77.84352112 69.31367769 63.95772838 72.89621378 50.06017218 74.43985389 75.70383957 108.9429297 137.4332324 79.79924185 102.4587331 31.44245711 46.60210805 32.25189936 2.10_390.1618m/z 2229.672477 2254.68141 2592.663465 2328.66853 1564.341061 1654.344955 1600.601771 1558.621656 2007.812064 1871.087284 1996.09357 53.06310699 1238.14102 2996.823596 2519.898769 2580.01257 161.4380369 864.2080795 1564.578533 1281.489004 1290.564699 2104.10625 1962.621176 70.41540458 62.41411382 48.13133531 9.53_497.2348m/z 778.1403644 685.8957858 672.0592785 651.7873843 555.1373533 506.5116339 498.6223643 463.3189309 786.2664551 773.5517645 831.5804228 1394.961932 284.8429041 227.0355172 418.67989 359.3160771 34.7005193 977.8080882 719.256957 52.29201602 156.3902034 631.0205091 439.4655877 0 0 0 3.21_429.2447m/z 259.596296 255.8132995 325.711114 313.4489101 273.4456511 268.9986789 262.7324986 268.1831106 365.6387568 319.5769287 349.5380732 24.99548965 212.0329394 369.6298138 316.7753347 315.9710033 0 246.4733102 284.7222602 262.5449566 279.0906285 369.968805 293.7965687 18.09104926 19.59414604 0 2.52_87.0450m/z 60.58170276 80.96768754 101.3872393 51.08138433 111.109199 116.4833739 116.1771168 89.69605306 111.6560273 108.2563021 117.9541058 0 94.75954572 113.4193361 105.3548355 99.85553377 0 85.08956567 47.51450872 77.52885049 91.57629431 69.94196005 86.11118781 0 0 0 2.65_456.2933m/z 148.8403921 116.5992955 164.5809438 132.5350902 101.23059 95.32305826 83.44192788 73.20396158 381.5612883 304.7447326 282.6839053 0 120.6416942 117.1171454 89.06663431 86.16436213 0 10.6361986 40.99978697 31.70862966 7.499767169 92.49126458 65.59738054 192.0939054 8.131583095 0 6.51_241.0168m/z 61.5824887 59.65897225 71.7660885 63.32744097 73.00448363 72.93877101 69.04239456 82.17373737 201.0705522 232.270844 238.8269621 320.7078388 266.924186 15.12989488 14.94343059 14.73311991 2.245551855 12.85860364 26.36712242 35.41731379 23.78249101 21.86396333 26.05157713 0 0 0 1.50_556.2957m/z 247.6598653 255.2143215 320.256391 222.3859967 286.1408776 231.7518099 290.6164978 273.7063198 405.7940828 253.9969965 322.6964209 0 668.047253 610.2962533 535.4965023 477.8096374 97.59408072 318.2577516 255.9802785 362.2149023 625.3756571 199.0914923 319.7258812 1.457921272 0.012593759 0 9.02_242.1142m/z 316.6628615 295.9205691 503.3220222 294.6726249 392.3982405 336.8105123 338.6770126 336.2863928 693.8804008 566.6510698 810.2403645 1012.202876 572.9574481 227.6853847 202.070995 177.1876829 188.3936354 330.1677553 277.80559 130.6996045 219.7918001 244.157897 162.1073677 2.844839109 3.69304288 30.07243626 3.51_291.0966m/z 116.5777222 108.8232792 159.1005513 118.2593239 182.2755263 181.7761623 209.5156159 191.9909689 128.1754858 140.2706227 126.9070292 0 328.749004 121.2447813 120.7660759 139.4551284 821.9225748 231.1715945 167.1169986 290.0713144 432.321621 160.0453714 193.5026092 111.8011246 288.1672306 126.6882231 1.55_507.3650m/z 228.8779422 211.8454161 229.5988407 178.065218 235.9011238 231.376659 271.1891883 198.5151187 167.4453851 111.9759299 107.1400056 0 51.81535596 377.4495289 298.2246742 279.0219632 0 275.9014147 257.0332963 361.6931929 381.3073708 271.0550337 402.584169 5.676744345 0 0 1.81_387.2728m/z 337.9168965 315.577656 381.4393598 329.1441597 540.6747423 511.3320873 525.6901879 491.4557509 232.8638963 256.3260748 254.0145778 0 440.7903917 655.5669431 529.8912884 588.8668064 0.417418766 596.0437941 486.6928417 705.3393187 892.1972701 457.7587711 601.9394936 0.509132585 0 0 6.71_141.0172m/z 14577.90354 15067.23996 18248.82821 16417.98378 25175.10162 24898.65977 25839.02821 26306.27385 11613.54216 11443.35346 11978.62038 12932.29367 16903.41213 24248.65006 22811.06147 23739.56936 20090.58164 28236.70902 22271.67454 30123.41015 38311.0582 20182.99896 24961.48423 5095.334399 5272.796711 3633.616101 1.59_195.1019m/z 115.1551579 106.350269 121.0871298 99.15655307 132.0069733 129.7227764 130.9779601 102.8012213 28.41585177 43.89391215 64.73441597 0 90.91052017 252.3765934 158.7106608 216.3019395 0 121.2420315 122.0023644 155.140597 187.8711923 162.0909461 141.2043709 0 0 0 2.65_458.3091m/z 292.989903 288.5643692 344.7261798 300.715165 251.20153 248.9302246 243.6520864 234.9207949 376.5134208 454.322911 341.4053073 0 270.0188812 688.5420217 631.5575632 607.990583 0 193.8917648 211.3874057 201.0200556 147.3118727 202.7470259 232.795213 0 2.554774846 0 1.74_129.0920m/z 566.6824127 595.3231777 669.7149642 612.771377 970.872282 915.9428889 985.0733909 1089.67204 640.2329885 528.184293 629.3966729 0 878.9429701 1196.129984 913.4041472 1146.276716 0 1242.783481 631.9876144 1060.645611 1449.420263 667.6708174 1086.010527 1.013090759 0 0 6.66_567.0040m/z 4786.887609 4740.291069 5608.694331 4974.192179 4369.322765 4422.096737 4399.13912 4762.827434 1633.523164 2672.898227 2324.135704 1923.693474 1809.510407 6151.727204 5752.751673 6102.286683 515.9980222 5836.748573 4523.636833 6096.323313 9244.926646 4442.981197 5865.373502 0.009663013 0.757386753 0.08672475 11.61_526.2519m/z 365.0286756 342.9211821 333.2280091 324.2689556 264.8113901 252.7392393 230.23736 226.516523 237.120257 274.5155085 498.1156488 548.4531068 68.85457888 102.9305555 210.2251194 166.278472 41.41257493 646.8713597 450.2110121 70.57298936 106.3318745 386.1559215 229.8529132 0 0 0 2.60_633.2916m/z 395.4350902 361.2042207 358.1515227 334.3387822 356.1604763 344.522601 310.7498241 331.1765177 181.4583866 102.0836885 127.546351 0 46.78457897 734.3469929 667.2873636 721.466319 0 217.3991777 513.8722515 328.7663472 208.6320156 737.6606155 545.7217499 0 18.5322157 0 3.29_243.1604m/z 75.72127319 82.54825302 102.7139831 80.81427335 105.8189479 104.8974404 97.49676532 103.7293798 287.0213893 271.0556442 279.1450709 105.7303177 382.1748116 34.28112614 29.99904193 29.11854017 0 23.07989982 36.02094526 36.43263906 46.82993892 42.56064969 41.04477393 1.580764363 40.39509863 0 2.37_453.2789m/z 53.89421291 48.99725462 70.09904521 58.17470475 54.8403471 58.6425677 49.69155429 49.0656263 129.4259296 105.3944114 131.7524203 0 107.6310304 61.41360502 48.2802827 44.08614643 0 24.3292167 39.79342702 37.21732761 32.29499771 49.93573453 54.23647259 0 0 0 1.84_509.3350m/z 73.73072324 69.63108963 93.19267913 87.03839482 91.15009105 91.12067656 70.10836632 112.3807643 104.7730536 132.965838 137.4013447 0 164.9688179 91.7027265 71.37658581 74.02633685 0 63.82470383 114.6234026 104.5286736 131.9516874 112.2486152 119.4706275 0 0 0 4.15_494.2181m/z 324.9073767 325.0942504 312.5938735 286.75425 198.8122397 195.6121217 196.4573338 178.4002358 420.4859001 167.5912701 133.3433486 801.781376 108.895972 368.4332701 306.2296887 336.6009503 46.40446984 112.7868138 243.3106435 268.5569703 204.7461789 406.6553046 272.0880489 0 0.00080417 17.86810394 1.40_654.4424m/z 283.5586914 332.241582 439.138339 329.8826917 560.3912315 577.6830132 516.7388888 712.4022705 201.4527756 115.9137375 141.5537312 0 70.89225659 797.7312452 731.1222886 737.0213092 0 688.5625259 598.5327958 674.2301196 1007.66285 497.6706974 647.2617956 0 0 0 1.91_564.3616m/z 9.574341365 7.409898339 12.90235935 10.85353082 13.21694946 10.91250566 19.23286214 3.872517764 160.1909415 116.1364023 130.181599 0 85.43398929 30.92880134 33.11093009 23.04608489 0 20.07914464 16.95315134 35.62085406 20.05068579 11.52955777 24.38357425 2.248186112 0 0 2.18_824.5973m/z 26.8595594 34.77628705 37.637541 42.44800469 62.12872314 69.23592199 71.51780332 66.16577342 475.9000696 253.5366199 254.4982603 0 508.5640376 0 0 0 0 0 0 0 0 0 0 0 0 0 3.26_351.1313m/z 223.6531696 235.113926 276.0913595 264.2975432 199.3204286 214.0109866 226.4543482 230.3560837 218.3687446 241.2788584 280.7594485 0.309761605 211.1427062 107.0217485 115.1585796 123.6419603 164.1751337 216.1890266 228.0638288 346.8379617 430.6827186 285.1807546 213.7840458 58.62525652 87.61415474 55.39357241 1.88_115.0764m/z 1278.296623 1175.725659 1411.856748 1308.420601 1669.902664 1493.179272 1548.412377 1756.387488 1099.071519 845.4250171 1376.396637 2.816143932 1282.232872 2440.094562 2058.242323 1559.755621 0 1794.853304 1239.037772 2546.27244 1986.900416 1470.218434 2457.305411 16.626909 2.527008506 0.899496172 2.35_185.0814m/z 71.62742843 65.60345339 80.92809316 74.11176239 97.67716214 103.6134015 103.8654534 111.9701704 100.3323371 84.76953208 92.85653192 22.16240982 154.3635293 85.37441693 80.2649775 81.53392295 0 95.71458144 84.81892556 115.9345474 190.6044956 98.00041762 96.06085444 18.10620302 45.8518891 4.170168976 1.38_345.2413m/z 1038.643452 1186.190018 1425.400061 1301.265976 1987.047915 2154.822126 2045.942086 2583.622213 440.0345575 225.2112023 302.6846686 0 220.8144526 1514.010746 1723.9455 1687.074956 653.8549384 2215.027368 2568.390109 2951.610151 2836.99134 1751.111727 1831.041804 61.0000443 0 0 1.69_451.3137m/z 97.20263419 98.47527667 117.403411 108.3915562 149.3905163 130.4699469 141.0532183 131.2976013 61.38084213 84.33299245 85.76168213 0 127.3379666 159.6006055 146.9059944 156.3709074 0 147.9773878 149.4412277 195.6999759 205.118966 144.4817897 184.0829968 0 0 0 1.43_295.2282m/z 119251.9161 122121.3478 149045.006 132145.0987 215802.503 216731.6287 230143.0466 233231.8719 46409.83946 41896.47651 48843.44092 0 77567.31676 194478.8854 185436.4553 190525.9354 212.3268071 226431.1829 184082.5304 249868.0009 326084.6576 183059.3736 232737.8701 107.2984255 442.6524128 156.7595667 2.79_281.2115m/z 63.41067226 54.96473335 61.18583673 60.35019506 56.23841837 54.7616439 55.39638946 57.25385024 158.7597317 160.4844782 156.5836465 1.371741082 138.1902333 50.04607679 62.24675534 42.51474311 0 27.31880939 48.1907062 46.88871775 51.75187424 36.60048103 49.94247441 0 0 0 1.62_313.2387m/z 65371.31379 64216.09292 79216.60412 68321.02773 107867.3964 105376.5352 111176.0639 113559.8673 43686.29257 45025.05622 47565.94317 0 74780.42503 113735.205 106090.5101 106513.9091 16.72005056 121920.7755 98404.05141 132365.1311 168747.1483 97353.53274 121548.7086 695.6604994 212.5490444 21.99953383 1.67_215.1649m/z 1307.311793 1397.193518 1607.255988 1612.655478 2372.315182 2328.000267 2510.463221 2560.33048 1410.765016 1270.801686 1308.8356 0 2417.473305 2122.403551 2114.048632 2037.238837 0 2561.207799 2091.148907 2762.511329 3802.910526 1990.925139 2561.80454 5.746378637 6.720284442 2.086132335 3.71_299.1850m/z 59.58094682 54.31720533 71.65943985 57.25715408 54.53250686 55.32976289 56.82518234 55.17603019 216.1371823 166.1688302 164.9241389 157.5110851 181.7940143 18.84795802 16.44976082 16.27963569 0 11.24867839 20.21415238 15.28312678 19.52977281 27.18589162 23.75338956 0 0 107.4314909 1.69_357.2629m/z 2838.892676 2897.89141 3505.029544 2931.278047 4450.10219 4314.486842 4772.341669 4567.285087 2691.407557 2385.097217 2533.153563 0 3894.151796 4835.979259 4359.485856 4367.620673 0 5077.112193 3991.733797 5492.963495 6719.569893 3993.45694 4894.123674 12.32174724 0 0 1.45_291.1963m/z 1065.893444 1322.11932 1626.786458 1377.985587 2161.645471 2383.122916 2513.213353 2614.466504 720.4875958 534.3204683 711.2538099 0 1097.184123 2746.004597 2112.876907 2546.596337 4.920644235 2724.411105 2060.367698 3232.160101 4175.559007 2165.994767 2809.889253 11.75080268 15.03641667 13.39256531 1.40_293.2120m/z 28159.43968 28730.60663 34799.87533 31339.24341 51244.05964 51965.10962 54788.99305 54995.8177 7402.803218 5621.57197 7317.497746 0 11204.71447 48066.47608 44544.89921 46164.96836 0.082315153 55542.82205 44685.22215 60162.9595 80321.97099 43761.66589 56243.51379 30.02452171 89.29233723 40.38201332 5.94_438.2318m/z 35.23454976 176.1245981 95.41232588 155.9640749 91.55027922 79.60121083 70.60632924 65.23806629 123.6262807 23.81652037 55.16098598 9.864438798 18.07712819 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