RefMet Compound Details

RefMet ID, RefMet name, exact mass and formula
RefMet ID	RM0136854
RefMet name	GAR
Systematic name	N-glycyl-D-ribofuranosylamine 5-(dihydrogen phosphate)
Synonyms	PubChem Synonyms
Exact mass	286.056606 (neutral)	Calculate m/z: (Choose adduct) [M+H]+ [M+H-H2O]+ [M.]+ [M+2H]2+ [M+3H]3+ [M+4H]4+ [M+K]+ [M+2K]2+ [M+2K-H]+ [M+Na]+ [M+2Na]2+ [M+2Na-H]+ [M+Li]+ [M+2Li]2+ [M+NH4]+ [M.CH3]+ [M+Ag]+ [M+H+CH3OH]+ [M+H+CH3CN]+ [M+H+2CH3CN]+ [M+Na+CH3CN]+ [M.NaFormate+H]+ [M.NH4Formate+H]+ [M.TMSi]+ [M.tBuDMSi]+ [M+H-Hexose]+ [M+H-EtnP]+ [M+H-SerP]+ [M-H]- [M-H-H2O]- [M-CH3]- [M-2H]2- [M-3H]3- [M-4H]4- [M+Cl]- [M+OAc]- [M+Na-2H]- [M+K-2H]- [M.Formate]- [M.NaFormate-H]- [M.NH4Formate-H]- [M.F]- [M-H-Ser]- [M.HF2]- M(neutral)    View other RefMet entries with this exact (neutral) mass:   +/- 0.05 amu   +/- 0.1 amu   +/- 0.2 amu   +/- 0.5 amu
Formula	C7H15N2O8P	View other entries in RefMet with this formula
Molecular descriptors
Molfile	51242 (Download molfile/View MW Metabolite Database details)
InChI
InChIKey	OBQMLSFOUZUIOB-SHUUEZRQSA-N	View other enantiomers/diastereomers of this metabolite in RefMet
SMILES	C(C(=O)N[C@H]1[C@@H]([C@@H]([C@@H](COP(=O)(O)O)O1)O)O)N Run Tanimoto similarity search (with similarity coefficient >=0.6)
Chemical/Biochemical Classification
Super Class	Nucleic acids
Main Class	Glycinamide ribonucleotides
Sub Class	Glycinamide ribonucleotides
Distribution of GAR in NMDR studies
Species	Plot Species distribution
Sample source	Plot Sample source(tissue) distribution
Platform	Platform (MS/NMR) used for detection
Chromatography	Chromatography methods used for detection
Studies	NMDR Studies reporting GAR
External Links
Pubchem CID	160913
ChEBI ID	18349
KEGG ID	C03838
HMDB ID	HMDB0002022
Structural annotation level
Annotation level	1   (1:Known structure; 2:Known regiochemistry; 3:Partial structure; 4:Sum-composition)

Table of KEGG reactions in human pathways involving GAR

Rxn ID	KEGG Reaction	Enzyme
R04144	ATP + 5-Phosphoribosylamine + Glycine <=> ADP + Orthophosphate + 5'-Phosphoribosylglycinamide	5-Phospho-D-ribosylamine:glycine ligase (ADP-forming)
R04325	10-Formyltetrahydrofolate + 5'-Phosphoribosylglycinamide <=> Tetrahydrofolate + 5'-Phosphoribosyl-N-formylglycinamide	10-formyltetrahydrofolate:5'-phosphoribosylglycinamide formyltransferase
R06974	Formate + ATP + 5'-Phosphoribosylglycinamide <=> ADP + Orthophosphate + 5'-Phosphoribosyl-N-formylglycinamide	formate:N1-(5-phospho-beta-D-ribosyl)glycinamide ligase (ADP-forming)

Table of KEGG human pathways containing GAR

Pathway ID	Human Pathway	# of reactions
hsa00230	Purine metabolism	2
hsa00670	One carbon pool by folate	1
hsa01100	Metabolic pathways	1